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They emit or absorb light. The electron in one orbit has a specific
amount of energy. The electron needs to have a different energy in
order to exist in a different orbit. When light shines on the atom,
if the electron can absorb just the right amount of energy from the
light, then it can jump to a different orbit.
Let me make up an example. Let us pretend that an atom has red
light shone upon it and it absorbs this and an electron jumps from 1S
to 2S. No matter how much red light you shine, the electron will
never jump further! Brighter light will allow more atoms to
have electrons jump from 1S to 2S, yet none go higher. But if I
shine, say, green light on the element, then electrons will jump from
1S to 2P. How odd! If I make the green light dimmer, fewer atoms
have an electron jump from 1S to 2P. If I make the green light
brighter, more atoms have an electron jump from 1S to 2P, but only
that transition. Further, it may be possible that after shining
bright red light on the atoms, I find that yellow light makes the 2S
electrons jump to 2P. Hmmm very suspicious!
Next: The Nature of Light
Up: The Color of Atoms
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Joseph Christensen
2001-05-02